Attempt synthesis of IR (I) metal complexes for catalytic conversion of glycerol to lactic acid
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comunitat-uji-handle2:10234/71324
comunitat-uji-handle3:10234/98504
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Título
Attempt synthesis of IR (I) metal complexes for catalytic conversion of glycerol to lactic acidAutoría
Tutor/Supervisor; Universidad.Departamento
Guisado Barrios, Gregorio; Universitat Jaume I. Departament de Química Inorgànica i OrgànicaFecha de publicación
2018-07Editor
Universitat Jaume IResumen
The aim of this research work is the synthesis of two novel iridium complexes containing
mesoionic triazolylidene ligands. The ultimate goal would imply the evaluation of their
performance in a very challenging ... [+]
The aim of this research work is the synthesis of two novel iridium complexes containing
mesoionic triazolylidene ligands. The ultimate goal would imply the evaluation of their
performance in a very challenging transformation such as the catalytic conversion of glycerol to
lactic acid.
The synthesis of the iridium complexes involves the synthesis of the ligand salt precursors that
will afford the desired corresponding metal complexes after deprotonation. Herein, two bistriazolium salts will be prepared. They are ready available after alkylation of the related bistriazole that can be obtained on big scale from ready available compounds.
To acquire new skills through the search and use scientific articles from different resources that
can be used for the design and synthesis of compounds that have not been described in the
literature.
On the other hand, there are other types of objectives in the realization of this research work,
such as gaining experience in a research laboratory, learning the use of some of the most
commonly used techniques in an Organometallic laboratory. Among them, is the use of Schlenk
techniques working with a glass manifold that allows to work under strict inert conditions, but
also the use of liquid nitrogen to carry out reactions at very low temperature.
To get familiar with the use of characterization techniques such as NMR and HR-MS
spectroscopy. In addition, improve skills in interpreting the results obtained in NMR
spectroscopy and mass spectroscopy. [-]
Palabras clave / Materias
Descripción
Treball Final de Grau en Química. Codi: QU0943. Curs acadèmic: 2017/2018
Tipo de documento
info:eu-repo/semantics/bachelorThesisDerechos de acceso
info:eu-repo/semantics/openAccess
Aparece en las colecciones
- Grau en Química [265]
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