Show simple item record

dc.contributor.authorKleinhans, George
dc.contributor.authorGuisado-Barrios, Gregorio
dc.contributor.authorPeris, Eduardo
dc.contributor.authorBezuidenhout, Daniela
dc.date.accessioned2018-06-25T10:07:15Z
dc.date.available2018-06-25T10:07:15Z
dc.date.issued2018
dc.identifier.issn0277-5387
dc.identifier.issn1873-3719
dc.identifier.urihttp://hdl.handle.net/10234/175324
dc.description.abstractThe preparation of a new neutral ruthenium(II) pincer complexes with formula [RuCl(CO)2(CTRZNCTRZ)] (CNC = bis(1,2,3-triazol-5-ylidene)carbazolide) is described. Access to the hydrido complex [RuH (CO)2(CTRZNCTRZ)] was attained by reaction of the pincer ligand precursor with base and with [RuCl(H) (AsPh3)3(CO)] in the presence of CO atmosphere. The meridional geometry pincer ligand in the complexes is confirmed by a single crystal X-ray diffraction study of [RuCl(CO)2(CTRZNCTRZ)]. Preliminary results of the use of [RuCl(CO)2(CTRZNCTRZ)] as catalyst in the transfer hydrogenation reaction of ketones, are reported.ca_CA
dc.format.extent6 p.ca_CA
dc.language.isoengca_CA
dc.publisherElsevierca_CA
dc.relation.isPartOfPolyhedron 143 (2018)ca_CA
dc.rights0277-5387/ © 2017 Elsevier Ltd. All rights reserved.ca_CA
dc.subjectRuthenium(II)ca_CA
dc.subjectMesoionic carbene (MIC)ca_CA
dc.subjectPincer ligandsca_CA
dc.subject1,2,3-Triazol-5-ylidene (TRZ)ca_CA
dc.subjectMeridional coordinationca_CA
dc.titleRuthenium(II) pincer complexes featuring an anionicCNC bis(1,2,3-triazol-5-ylidene)carbazolide ligand coordinatedin a meridional fashionca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttps://doi.org/10.1016/j.poly.2017.07.010
dc.relation.projectIDIJCI-2015- 23407 ; CTQ2014-51999-P ; P11B2014-02 ;ca_CA
dc.rights.accessRightsinfo:eu-repo/semantics/embargoedAccessca_CA
dc.relation.publisherVersionhttps://www.sciencedirect.com/science/article/pii/S027753871730493Xca_CA
dc.date.embargoEndDate2019-07-15
dc.type.versioninfo:eu-repo/semantics/publishedVersionca_CA


Files in this item

Thumbnail

This item appears in the following Collection(s)

Show simple item record