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High-Fidelity, Narcissistic Self-Sorting in the Synthesis of Organometallic Assemblies from Poly-NHC Ligands
dc.contributor.author | Sinha, Narayan | |
dc.contributor.author | Tan, Tristan T. Y. | |
dc.contributor.author | Peris, Eduardo | |
dc.contributor.author | Hahn, Franz Ekkehardt | |
dc.date.accessioned | 2017-11-16T11:45:53Z | |
dc.date.available | 2017-11-16T11:45:53Z | |
dc.date.issued | 2017-05 | |
dc.identifier.citation | SINHA, Narayan, et al. High‐Fidelity, Narcissistic Self‐Sorting in the Synthesis of Organometallic Assemblies from Poly‐NHC Ligands. Angewandte Chemie International Edition, 2017. | ca_CA |
dc.identifier.uri | http://hdl.handle.net/10234/170128 | |
dc.description.abstract | Highly selective, narcissistic self-sorting has been observed in the one-pot synthesis of three organometallic molecular cylinders of type [M3{L-(NHC)3}2](PF6)3 (M=Ag+, Au+; L=1,3,5-benzene, triphenylamine, or 1,3,5-triphenylbenzene) from L-(NHC)3 and silver(I) or gold(I) ions. The molecular cylinders contain only one type of tris-NHC ligand with no crossover products detectable. Transmetalation of the tris-NHC ligands from Ag+ to Au+ in a one-pot reaction with retention of the supramolecular structures is also demonstrated. High-fidelity self-sorting was also observed in the one-pot reaction of benzene-bridged tris-NHC and tetrakis-NHC ligands with Ag2O. This study for the first time extends narcissistic self-sorting in metal–ligand interactions from Werner-type complexes to organometallic derivatives. | ca_CA |
dc.format.extent | 4 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.rights | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | narcissistic self-sorting | ca_CA |
dc.subject | organometallic complexes | ca_CA |
dc.subject | poly-NHC ligands | ca_CA |
dc.subject | silver and gold | ca_CA |
dc.subject | supramolecular chemistry | ca_CA |
dc.title | High-Fidelity, Narcissistic Self-Sorting in the Synthesis of Organometallic Assemblies from Poly-NHC Ligands | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/anie.201702637 | |
dc.relation.projectID | DFG (Deutsche Forschungsgemeinschaft) (SFB 858, IRTG 2027), MIMECO (Spain) (CTQ 2014-51999-P) and Universitat Jaume I (P11B2014-02). | ca_CA |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/anie.201702637/full | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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