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dc.contributor.authorVentura Espinosa, David
dc.contributor.authorCarretero Cerdán, Alba
dc.contributor.authorBaya, Miguel
dc.contributor.authorGarcía, Hermenegildo
dc.contributor.authorMata Martínez, Jose A
dc.date.accessioned2017-09-11T07:24:02Z
dc.date.available2017-09-11T07:24:02Z
dc.date.issued2017
dc.identifier.citationVENTURA‐ESPINOSA, David, et al. Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On‐demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier. Chemistry-A European Journal, 2017, vol. 23, no 45, p. 10815-10821.ca_CA
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.urihttp://hdl.handle.net/10234/168667
dc.description.abstractThe compound [Ru(p-cym)(Cl)2(NHC)] is an effective catalyst for the room-temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on-demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non-toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.ca_CA
dc.format.extent7 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherWileyca_CA
dc.rights© 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheimca_CA
dc.rights.urihttp://rightsstatements.org/vocab/InC/1.0/*
dc.subjectdehydrogenative couplingca_CA
dc.subjecthydrogenca_CA
dc.subjecthydrosilanesca_CA
dc.subjecthydrogen generationca_CA
dc.subjectrutheniumca_CA
dc.titleCatalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrierca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1002/chem.201700243
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionChemistry-A European Journal, 2017, vol. 23, no 45ca_CA
dc.relation.publisherVersionhttp://onlinelibrary.wiley.com/doi/10.1002/chem.201700243/full
dc.contributor.funderThe authors thank the financial support from MINECO (CTQ2015-69153-C2-1-R, CTQ2015-69153-C2-2-R and CTQ2015-67461-P), Generalitat Valenciana (AICO/2015/039), Diputación General de Aragón (Grupo Consolidado E21) and Universitat Jaume I (P1.1B2015-09). D. V-E thanks the MINECO for the FPU grant (FPU15/03011). The authors are very grateful to the ‘Serveis Centrals d'Instrumentació Científica (SCIC)′ of the Universitat Jaume I and to the Instituto de Biocomputación y Física de Sistemas Complejos (BIFI) and the Centro de Supercomputación de Galicia (CESGA) for generous allocation of computational resources.ca_CA
dc.type.versioninfo:eu-repo/semantics/acceptedVersionca_CA


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