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Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier
dc.contributor.author | Ventura Espinosa, David | |
dc.contributor.author | Carretero Cerdán, Alba | |
dc.contributor.author | Baya, Miguel | |
dc.contributor.author | García, Hermenegildo | |
dc.contributor.author | Mata Martínez, Jose A | |
dc.date.accessioned | 2017-09-11T07:24:02Z | |
dc.date.available | 2017-09-11T07:24:02Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | VENTURA‐ESPINOSA, David, et al. Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On‐demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier. Chemistry-A European Journal, 2017, vol. 23, no 45, p. 10815-10821. | ca_CA |
dc.identifier.issn | 0947-6539 | |
dc.identifier.issn | 1521-3765 | |
dc.identifier.uri | http://hdl.handle.net/10234/168667 | |
dc.description.abstract | The compound [Ru(p-cym)(Cl)2(NHC)] is an effective catalyst for the room-temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on-demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non-toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC. | ca_CA |
dc.format.extent | 7 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.rights | © 2017 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | dehydrogenative coupling | ca_CA |
dc.subject | hydrogen | ca_CA |
dc.subject | hydrosilanes | ca_CA |
dc.subject | hydrogen generation | ca_CA |
dc.subject | ruthenium | ca_CA |
dc.title | Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/chem.201700243 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | Chemistry-A European Journal, 2017, vol. 23, no 45 | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/chem.201700243/full | |
dc.contributor.funder | The authors thank the financial support from MINECO (CTQ2015-69153-C2-1-R, CTQ2015-69153-C2-2-R and CTQ2015-67461-P), Generalitat Valenciana (AICO/2015/039), Diputación General de Aragón (Grupo Consolidado E21) and Universitat Jaume I (P1.1B2015-09). D. V-E thanks the MINECO for the FPU grant (FPU15/03011). The authors are very grateful to the ‘Serveis Centrals d'Instrumentació Científica (SCIC)′ of the Universitat Jaume I and to the Instituto de Biocomputación y Física de Sistemas Complejos (BIFI) and the Centro de Supercomputación de Galicia (CESGA) for generous allocation of computational resources. | ca_CA |
dc.type.version | info:eu-repo/semantics/acceptedVersion | ca_CA |
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