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Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization
dc.contributor.author | Sokolov, Maxim | |
dc.contributor.author | Anyushin, Alexander V. | |
dc.contributor.author | Hernández Molina, Rita | |
dc.contributor.author | Llusar, Rosa | |
dc.contributor.author | García Basallote, Manuel | |
dc.date.accessioned | 2017-06-23T10:00:53Z | |
dc.date.available | 2017-06-23T10:00:53Z | |
dc.date.issued | 2017 | |
dc.identifier.citation | Sokolov, Maxim N., Alexander V. Anyushin, Rita Hernandez-Molina, et al. 2017. Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization. Pure and Applied Chemistry. 89(3): 379-392. Retrieved 23 Jun. 2017, from doi:10.1515/pac-2017-0105 | ca_CA |
dc.identifier.issn | 0033-4545 | |
dc.identifier.issn | 1365-3075 | |
dc.identifier.uri | http://hdl.handle.net/10234/168077 | |
dc.description.abstract | This contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed. | ca_CA |
dc.format.extent | 13 p. | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | De Gruyter | ca_CA |
dc.relation.isPartOf | Pure and Applied Chemistry, Volume 89, Issue 3 (Mar 2017) | ca_CA |
dc.rights | © 2017 IUPAC & De Gruyter. This work is licensed under a Creative Commons Attribution-NonCommercial-NoDerivatives 4.0 International License | |
dc.rights.uri | http://creativecommons.org/licenses/by-nc-nd/4.0/ | |
dc.subject | ICPC-21 | ca_CA |
dc.title | Hydroxylated phosphines as ligands for chalcogenide clusters: self assembly, transformations and stabilization | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | https://doi.org/10.1515/pac-2017-0105 | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | https://www.degruyter.com/view/j/pac.2017.89.issue-3/pac-2017-0105/pac-2017-0105.xml?rskey=CxBl2j&result=1&q=10.1515%2Fpac-2017-0105 | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
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