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One step microwave-assisted synthesis of nanocrystalline WOx–ZrO2 acid catalysts
dc.contributor.author | Gonell, Francisco | |
dc.contributor.author | Portehault, David | |
dc.contributor.author | Julian-Lopez, Beatriz | |
dc.contributor.author | Vallé, Karine | |
dc.contributor.author | Sánchez, Clément | |
dc.contributor.author | CORMA, AVELINO | |
dc.date.accessioned | 2017-05-09T08:00:05Z | |
dc.date.available | 2017-05-09T08:00:05Z | |
dc.date.issued | 2016 | |
dc.identifier.citation | GONELL, Francisco, et al. One step microwave-assisted synthesis of nanocrystalline WO x–ZrO 2 acid catalysts. Catalysis Science & Technology, 2016, vol. 6, no 23, p. 8257-8267. | ca_CA |
dc.identifier.issn | 2044-4753 | |
dc.identifier.issn | 2044-4761 | |
dc.identifier.uri | http://hdl.handle.net/10234/167495 | |
dc.description.abstract | Nanocrystalline ZrO2 and WOx–ZrO2 catalysts with good control over the zirconia phase and the nature of the W species were synthesized by a microwave-assisted aqueous route. The monoclinic ZrO2 (m-ZrO2) and tetragonal ZrO2 (t-ZrOz) polymorphs were isolated through accurate control of the synthetic conditions, in acidic and basic media, respectively. The evolution of the zirconia and W species under annealing of the WOx–ZrO2 nanocomposites at 500 °C and 800 °C was studied, and the resulting materials were tested as catalysts for aldoxime dehydration and hydration of alkynes for the production of nitriles and carbonyls, respectively. In the dehydration reaction, the most active species are W(VI) in tetrahedral coordination, independently of the ZrO2 polymorph, while in the hydration reaction the zirconia phase plays a key role, as the tungsten doped t-ZrO2 appears to be the most active catalyst. | ca_CA |
dc.description.sponsorShip | F. G. is grateful to Ministerio de Educación, Cultura y Deporte for his PhD grant (AP2010-2748); B. J.-L. and F. G. thank the Spanish Government (MAT2011-27008 project) and University Jaume I (UJI, P1 1B2014-21). F. G. and A. C. thank financial support from Spanish Government-MINECO through “Severo Ochoa” (SEV 2012-0267). D. P., C. S. and K. V. would like to strongly acknowledge the Foundation du Collège de France for support and thank the French Commissariat à l'Energie Atomique et aux Energies Alternatives for financial support. SCIC from Universitat Jaume I and Servicio de Microscopía Electrónica at Universitat Politècnica de València are also acknowledged for instrumental facilities. | ca_CA |
dc.format.extent | 11 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Catalysis Science & Technology, 2016, vol. 6, no 23 | ca_CA |
dc.rights | This journal is © The Royal Society of Chemistry 2016. GONELL, Francisco, et al. One step microwave-assisted synthesis of nanocrystalline WO x–ZrO 2 acid catalysts, 2016. DOI: http://dx.doi.org/10.1039/c6cy01082b. Reproduced by permission of The Royal Society of Chemistry. | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | nanocrystalline ZrO2 | ca_CA |
dc.subject | WOx-ZrO2 catalysts | ca_CA |
dc.subject | zirconia | ca_CA |
dc.subject | heterogeneous catalyst | ca_CA |
dc.title | One step microwave-assisted synthesis of nanocrystalline WOx–ZrO2 acid catalysts | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1039/C6CY01082B | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.rsc.org/en/content/articlelanding/2016/cy/c6cy01082b#!divAbstract | ca_CA |
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