Insight into Copper-Based Catalysts: Microwave-Assisted Morphosynthesis, In Situ Reduction Studies, and Dehydrogenation of Ethanol
Impacto
Scholar |
Otros documentos de la autoría: Volanti, Diogo P.; Sato, André G.; Orlandi, Marcelo; Bueno, José M. C.; Longo, Elson; Andres, Juan
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http://dx.doi.org/10.1002/cctc.201000462 |
Metadatos
Título
Insight into Copper-Based Catalysts: Microwave-Assisted Morphosynthesis, In Situ Reduction Studies, and Dehydrogenation of EthanolAutoría
Fecha de publicación
2011Editor
WileyISSN
1867-3880Cita bibliográfica
Volanti, D. P., Sato, A. G., Orlandi, M. O., Bueno, J. M. C., Longo, E. and Andrés, J. (2011), Insight into Copper-Based Catalysts: Microwave-Assisted Morphosynthesis, In Situ Reduction Studies, and Dehydrogenation of Ethanol. ChemCatChem, 3: 839–843. doi:10.1002/cctc.201000462Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://onlinelibrary.wiley.com/doi/10.1002/cctc.201000462/abstractVersión
info:eu-repo/semantics/publishedVersionPalabras clave / Materias
Resumen
Copper-based catalysts obtained by microwave-assisted morphosynthesis were correlated with the dehydrogenation of ethanol. The degree of reduction was monitored using time-resolved in situ XANES during TPR under H2. ... [+]
Copper-based catalysts obtained by microwave-assisted morphosynthesis were correlated with the dehydrogenation of ethanol. The degree of reduction was monitored using time-resolved in situ XANES during TPR under H2. A semiquantitative estimation of the different chemical forms (Cu2+, Cu+, and/or Cu0) was obtained. The results suggest intrinsic particularities due to different morphologies at the active state in reduction kinetics. [-]
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ChemCatChem, 2011, 3Derechos de acceso
Copyright 2011 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim
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