Show simple item record

dc.contributor.authorSilva, Gabriela S.
dc.contributor.authorGracia Edo, Lourdes
dc.contributor.authorFabbro, Maria T.
dc.contributor.authorSerejo Dos Santos, Luis P.
dc.contributor.authorBeltrán Mir, Héctor
dc.contributor.authorCordoncillo, Eloisa
dc.contributor.authorLongo, Elson
dc.contributor.authorAndrés, Juan
dc.date.accessioned2016-11-04T16:19:53Z
dc.date.available2016-11-04T16:19:53Z
dc.date.issued2016
dc.identifier.citationSILVA, Gabriela S., et al. Theoretical and Experimental Insight on Ag2CrO4 Microcrystals: Synthesis, Characterization, and Photoluminescence Properties. Inorganic Chemistry, 2016, vol. 55, no 17, p. 8961-8970.ca_CA
dc.identifier.issn0020-1669
dc.identifier.issn1520-510X
dc.identifier.urihttp://hdl.handle.net/10234/164028
dc.description.abstractAg2CrO4 microcrystals were synthesized by means of the coprecipitation method without the use of a surfactant under three different conditions. On the basis of the theoretical and experimental results, we describe the relationship among the structural order/disorder effects, morphology, and photoluminescence of the Ag2CrO4 microcrystals. The experimental results were correlated with the theoretical findings for a deeper understanding of the relationship between the electronic structure, morphology, and photoluminescence properties. First-principles computational studies were used to calculate the geometries of bulk Ag2CrO4 and its low-index (001), (011), (110), (010), (111), and (100) facets based on a slab model. A good agreement between the experimental and the theoretical morphologies was found by varying the ratio of the superficial energy values.ca_CA
dc.description.sponsorShipThis work was financially supported by Brazilian research financing institutions (CNPq (304531/2013-8; 237944/2012- 0), FAPESP (2013/07296-2; 2013/26671-9), and CAPES (PNPD-1268069)), Spanish research funding institutions (CTQ2012-36253-C03-02 project (Ministerio de Economia y Competitividad)), PrometeoII/2014/022, ACOMP/2014/270 projects (Generalitat Valenciana), and Programa de Cooperación Cientifíca con Iberoamerica (Brasil) of Ministerio de Educación (PHBP14-00020). We also acknowledge Servei Informática, Universitat Jaume I, for the generous allotment of computer time. J.A. acknowledges the Ministerio de Economia y Competitividad, “Salvador Madariaga” program, PRX15/ 00261. L.G. acknowledges Banco Santander (Becas Iberoamérica: Jóvenes profesores e investigadores).ca_CA
dc.format.extent10 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherAmerican Chemical Societyca_CA
dc.relation.isPartOfInorganic Chemistry, 2016, vol. 55, núm. 17ca_CA
dc.rightsCopyright © 2016 American Chemical Societyca_CA
dc.subjectGeneralized gradient approximationca_CA
dc.subjectPhotocatalytic propertiesca_CA
dc.subjectSilver chromateca_CA
dc.subjectCoprecipitation methodca_CA
dc.subjectSonochemical synthesisca_CA
dc.titleTheoretical and Experimental Insight on Ag2CrO4 Microcrystals: Synthesis, Characterization, and Photoluminescence Propertiesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1021/acs.inorgchem.6b01452
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://bs8lz6ys5q.search.serialssolutions.com/?ctx_ver=Z39.88-2004&ctx_enc=info%3Aofi%2Fenc%3AUTF-8&rfr_id=info%3Asid%2Fsummon.serialssolutions.com&rft_val_fmt=info%3Aofi%2Ffmt%3Akev%3Amtx%3Ajournal&rft.genre=article&rft.atitle=Theoretical+and+experimental+insight+on+Ag.sub.2CrO.sub.4+microcrystals%3A+synthesis%2C+characterization%2C+and+photoluminescence+properties&rft.jtitle=Inorganic+Chemistry&rft.au=Silva%2C+Gabriela+S&rft.au=Gracia%2C+Lourdes&rft.au=Fabbro%2C+Maria+T&rft.au=Santos%2C+Luis+P.+Serejo+dos&rft.date=2016-09-06&rft.pub=American+Chemical+Society&rft.issn=0020-1669&rft.eissn=1520-510X&rft.volume=55&rft.issue=17&rft.spage=8961&rft.externalDBID=BKMMT&rft.externalDocID=467116234&paramdict=es-ESca_CA


Files in this item

FilesSizeFormatView

There are no files associated with this item.

This item appears in the following Collection(s)

Show simple item record