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dc.contributor.authorAraujo, Marco
dc.contributor.authorMuñoz Capdevila, Iván
dc.contributor.authorDiaz-Oltra, Santiago
dc.contributor.authorEscuder, Beatriu
dc.date.accessioned2016-07-29T07:22:07Z
dc.date.available2016-07-29T07:22:07Z
dc.date.issued2016-06
dc.identifier.citationARAÚJO, Marco, et al. Tandem Catalysis of an Aldol-‘Click’Reaction System within a Molecular Hydrogel. Molecules, 2016, vol. 21, no 6, p. 744.ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/162064
dc.description.abstractA heterogeneous supramolecular catalytic system for multicomponent aldol-‘click’ reactions is reported. The copper(I) metallohydrogel functionalized with a phenyltriazole fragment was able to catalyze the multicomponent reaction between phenylacetylene, p-nitrobenzaldehyde, and an azide containing a ketone moiety, obtaining the corresponding aldol products in good yields. A possible mechanistic pathway responsible for this unexpected catalytic behavior has been proposed.ca_CA
dc.description.sponsorShipThis work was supported by the EU (Marie Curie ITN-Smartnet, Grant PITN-GA- 2012-316656). M. A. thanks EU for an ESR Marie Curie contract.ca_CA
dc.format.extent13 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherMDPIca_CA
dc.relation.isPartOfMolecules 2016, 21(6)ca_CA
dc.rights© 1996-2016 MDPI AG (Basel, Switzerland) unless otherwise statedca_CA
dc.rightsAtribución 4.0 España*
dc.rights.urihttp://creativecommons.org/licenses/by-sa/4.0/*
dc.subjectaldol additionca_CA
dc.subjectclick reactionca_CA
dc.subjecttandem catalysisca_CA
dc.subjectsupramolecular gelsca_CA
dc.subjectmulticomponent systemca_CA
dc.titleTandem Catalysis of an Aldol-'Click' Reaction System within a Molecular Hydrogelca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.3390/molecules21060744
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://www.mdpi.com/1420-3049/21/6/744ca_CA


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