• openAccess   A Shape‐Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes 

      Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo Wiley (2018-10-01)
      The development of three‐dimensional supramolecular coordination complexes (SCCs), with cavities suitable for guest binding, is of great interest because these materials are useful in a large number of applications. Herein, ...
    • openAccess   Clippane: A Mechanically Interlocked Molecule (MIM) Based on Molecular Tweezers 

      Ibáñez, Susana; Vicent Barrera, Cristian; Peris, Eduardo Wiley (2022-01-10)
      In this study we report the preparation of a new mechanically interlocked molecule formed by the self-aggregation of two metallotweezers composed by two pyrene-imidazolylidene gold(I) arms and a pyridine-centered pentacyclic ...
    • openAccess   Guest-shuttling in a nanosized metallobox 

      Ibáñez, Susana; Salvà, Paula; Dawe, Louise N.; Peris, Eduardo Wiley (2024-01-05)
      An iridium-conjoined long and narrow metallorectangle was obtained by combining a quinoxalinophenanthrophenazine-connected Janus-di-imidazolylidene ligand and pyrazine. The size and shape of this assembly together with the ...
    • openAccess   Platinum-Based Organometallic Folders for the Recognition of Electron-Deficient Aromatic Substrates 

      Nuevo Vialás, Daniel; Gonell, Sergio; Poyatos, Macarena; Peris, Eduardo Wiley (2017-05-29)
      A series of platinum complexes with cis-oriented polyaromatic N-heterocyclic carbene ligands were prepared and characterized. The relative disposition of the polyaromatic ligands about the metal cause these compounds to ...
    • openAccess   Self-Assembly of Di-N-Heterocyclic Carbene-Gold-Adorned Corannulenes on C60 

      Mejuto, Carmen; Escobar, Luis; Guisado-Barrios, Gregorio; Ballester, Pablo; Goussev, Dmitri; Peris, Eduardo Wiley (2017-08-04)
      The deprotonation of a corannulene-based bisazolium salt allowed the preparation of a corannulene-based NHC di-AuI complex. The prepared di-AuI-complex was tested in the recognition of fullerene-C60, demonstrating good ...
    • openAccess   Shape-Adaptability and Redox-Switching Properties of a Di-Gold Metallotweezer 

      Ibáñez, Susana; Peris, Eduardo Wiley (2021-04-12)
      The use of a carbazolyl-connected di-gold(I) metallotweezer for the encapsulation of several electron-poor organic substrates, and a planar Au(III) complex containing a CNC pincer ligand, is described. The binding affinity ...
    • openAccess   The New Di-Gold Metallotweezer Based on an Alkynylpyridine System 

      Ibáñez, Susana MDPI (2022-06-02)
      We developed a simple method to prepare one gold-based metallotweezer with two planar Au-pyrene-NHC arms bound by a 2,6-bis(3-ethynyl-5-tert-butylphenyl)pyridine unit. This metallotweezer is able to bind a series of ...