Listar Institute of Advanced Materials (INAM) por título
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A Matter of Fidelity: Self‐Sorting Behavior of Di‐Gold Metallotweezers
Wiley (2019-06)Cation‐induced high selective self‐sorting is observed for reactions involving a series of di‐gold metallotweezers. The variation of the nature of the arms of the tweezers (benzo‐imidazolylidene or pyrene‐imidazolylidene), ... -
A metal-organic framework converted catalyst that boosts photo-electrochemical water splitting
Royal Society of Chemistry (2019-04-08)Realization of photo-electrochemical water splitting to generate H2 alternative fuel requires the facilitation of the kinetically-sluggish oxygen evolution reaction (OER) occurring at the photoanode. To do so, there is a ... -
A palladium-hinged organometallic square with a perfect-sized cavity for the encapsulation of three heteroguests
Royal Society of Chemistry (2019-12-25)A nanometer-sized tetrapalladium metallosquare with a pyrene-bisimidazolylidene ligand was found to display a perfect-sized cavity for the encapsulation of three heteroguests, enabling the formation of quintuple D–A–D–A–D ... -
A Perovskite Photovoltaic Mini-Module-CsPbBr3 Photoelectrochemical Cell Tandem Device for Solar-Driven Degradation of Organic Compounds
American Chemical Society (2023-10-02)Recently, halide perovskites have been widely explored for high-efficiency photocatalysis or photoelectrochemical (PEC) cells. Here, in order to make an efficient photoanode electrode for the degradation of pollutants, ... -
A Perspective on the Commercial Viability of Perovskite Solar Cells
Wiley (2021-11-04)Perovskite solar cells (PSCs) have received a large amount of research funds due to their potential as a frontrunner in a new generation of solar cells; consequently, the desire to commercialize this technology is mounting. ... -
A Platinum molecular complex immobilised on the surface of graphene as active catalyst in alkyne hydrosilylation
Wiley (2020-05-11)Abstract A platinum complex bearing a N‐heterocyclic carbene (NHC) ligand functionalised with a pyrene‐tag is immobilised onto the surface of reduced graphene oxide (rGO). The hybrid material composed of an organometallic ... -
A QM/MM study on the origin of retro-aldolase activity of a catalytic antibody
The Royal Society of Chemistry (2021-04-26)The retro-aldolase mechanism of methodol catalysed by the catalytic antibody 33F12 is described based on the exploration of the free energy landscape obtained with QM/MM methods. The amino acids involved in the reaction ... -
A Rational Approach to Improve the Overall Performances of Semitransparent Perovskite Solar Cells by Electrode Optical Management
American Chemical Society (2024)Improving the overall characteristics of semitransparent solar cells (STSCs) is a very hard goal, not only because the absorption and the transmission of light through the device are two competitive processes but also ... -
A redox-switchable catalyst with an 'unplugged' redox tag
Royal Society of Chemistry (2022-08-24)Two bis-(propyl-imidazolium)-napthalenediimide (NDI) salts were prepared and used as N-heterocyclic carbene (NHC) precursors for the preparation of dimetallic complexes of rhodium and iridium. Infrared spectroelectrochemical ... -
A Redox-Switchable Gold(I) Complex for the Hydroamination of Acetylenes: A Convenient Way for Studying Ligand-Derived Electronic Effects
American Chemical Society (2022-03-31)A gold complex with a naphthalene-di-imide-functionalized N-heterocyclic carbene (NHC) ligand was prepared and characterized. The electrochemical studies reveal that the complex is able to undergo two successive reduction ... -
A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
Royal Society of Chemistry (2020-03-14)A tetrabenzoimidazolium-resorcinarene cavitand was used for the preparation of a tetra-benzoimidazolylidene of rhodium, which is unprecedented in the field of poly-NHC metal complexes. Both, the experimental and computational ... -
A Rigid Trigonal‐Prismatic Hexagold Metallocage That Behaves as a Coronene Trap
Wiley (2019-05-13)A trigonal‐prismatic hexagold cage was obtained by combining a triphenylene‐tris(N‐heterocyclic carbene) ligand and a carbazolyl‐bis(alkynyl) linker. The metallocage has a slot‐like cavity with a volume of about 300 Å3. ... -
A Shape‐Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes
Wiley (2018-10-01)The development of three‐dimensional supramolecular coordination complexes (SCCs), with cavities suitable for guest binding, is of great interest because these materials are useful in a large number of applications. Herein, ... -
A Size‐Flexible Organometallic Box for the Encapsulation of Fullerenes
Wiley (2019-04-19)A palladium‐cornered molecular square with four pyrene‐bis(imidazolylidene) bridging ligands is reported. This metallo‐polygon can encapsulate C60 and C70. The X‐ray diffraction structures of the empty cage as well as the ... -
A soft-chemistry route to prepare halide perovskite nanocrystals with tunable emission and high optical performance
Springer (2023)Cesium lead halide perovskites constitute a benchmark family of inorganic perovskites for high performance optoelectronic devices. Hot injection is by far the most extended procedure to fabricate CsPbX3 (X: Cl, Br, and/or ... -
A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
Wiley (2023-05-12)The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially ... -
A Twisted Tetragold Cyclophane from a Fused BisImidazolindiylidene
American Chemical Society (2019)The reaction between an angular bis-imidazolidinium salt and [AuCl(SMe)2] allowed the preparation of a discrete digold complex, with a rigid angular bridging bis-imidazolindiylidene ligand. This complex reacts with ... -
ABA Supplementation Rescues IRS2 and BDNF mRNA Levels in a Triple-Transgenic Mice Model of Alzheimer’s Disease
IOS Press (2023-09-08)Insulin resistance underlies Alzheimer’s disease (AD) by affecting neuroinflammation and brain-derived neurotrophic factor (BDNF) expression. Here, we evaluated the effect of early and late-start abscisic acid (ABA) ... -
Abiotic depletion and the potential risk to the supply of cesium
Elsevier (2020-10)The petroleum exploration industry is the largest end user of cesium where it is employed in oil well drilling fluid. It has recently been broadly reported that the inclusion of cesium into perovskite for photovoltaics and ...