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Selective Interaction of Dopamine with the Self-Assembled Fibrillar Network of a Molecular Hydrogel Revealed by STD-NMR
dc.contributor.author | Segarra Maset, María Dolores | |
dc.contributor.author | Escuder, Beatriu | |
dc.contributor.author | Miravet, Juan | |
dc.date.accessioned | 2016-04-29T11:05:42Z | |
dc.date.available | 2016-04-29T11:05:42Z | |
dc.date.issued | 2015-09-28 | |
dc.identifier.citation | SEGARRA‐MASET, María D.; ESCUDER, Beatriu; MIRAVET, Juan F. Selective Interaction of Dopamine with the Self‐Assembled Fibrillar Network of a Molecular Hydrogel Revealed by STD‐NMR. Chemistry–A European Journal, 2015, vol. 21, no 40, p. 13925-13929 | ca_CA |
dc.identifier.issn | 0947-6539 | |
dc.identifier.uri | http://hdl.handle.net/10234/159042 | |
dc.description.abstract | A molecular hydrogel formed by a derivative of L-valine with pendant isonicotinoyl moieties interacts selectively with protonated dopamine in the presence of related compounds such as 3-methylcatechol, and protonated or neutral phenethylamine. A two-point interaction with the gel fibers is postulated to explain the results. The conclusions are obtained from nuclear magnetic resonance saturation transfer experiments (STD-NMR), illustrating how this technique is perfectly suited to monitor the interaction of substrates with the fibrillar network of a molecular gel. | ca_CA |
dc.description.sponsorShip | Ministry of Science and Innovation of Spain (grant CTQ2012-37735) and Universitat Jaume I (grants P1.1B2012-25 and P1.1B2013-57) are acknowledged for financial support. Jesús Angulo from University of East Anglia, Norwich, UK, is thanked for helpful insight into STD experiments. | ca_CA |
dc.format.extent | 5 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | Chemistry–A European Journal, 2015, vol. 21, no 40 | ca_CA |
dc.rights | © 2015 Wiley-VCH Verlag GmbH &Co. KGaA, Weinheim | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | hydrogels | ca_CA |
dc.subject | molecular recognition | ca_CA |
dc.subject | NMR spectroscopy | ca_CA |
dc.subject | soft materials | ca_CA |
dc.subject | supramolecular chemistry | ca_CA |
dc.title | Selective Interaction of Dopamine with the Self-Assembled Fibrillar Network of a Molecular Hydrogel Revealed by STD-NMR | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/chem.201502018 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/chem.201502018/full | ca_CA |
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