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Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
dc.contributor.author | Mejuto, Carmen | |
dc.contributor.author | García-Eleno, Marco A. | |
dc.contributor.author | Guisado-Barrios, Gregorio | |
dc.contributor.author | Spasyuk, Denis | |
dc.contributor.author | Gusev, Dmitry | |
dc.contributor.author | Peris, Eduardo | |
dc.date.accessioned | 2015-12-11T08:32:52Z | |
dc.date.available | 2015-12-11T08:32:52Z | |
dc.date.issued | 2015-06 | |
dc.identifier.citation | Mejuto, C., García-Eleno, M. A., Guisado-Barrios, G., Spasyuk, D., Gusev, D., & Peris, E. (2015). Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties. Organic Chemistry Frontiers, 2(8), 936-941. | ca_CA |
dc.identifier.issn | 2052-4110 | |
dc.identifier.uri | http://hdl.handle.net/10234/143245 | |
dc.description.abstract | 1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic [Ru(NNC)(CO3)(PPh3)] complex, or the [Ru(μ-Cl)(NNC)]2(2Cl−) dimer, was obtained. A di-silver complex in which two ligands are monocoordinated to the metal center through the NHC groups was also obtained and characterised. The dimetallic ruthenium complex reacts with alcohols yielding a monohydride species. The preliminary studies on the catalytic activity of the ruthenium dimer indicate that the complex is active in the reduction of ketones and aldehydes under transfer hydrogenation conditions. | ca_CA |
dc.description.sponsorShip | MINECO (CTQ2014-51999-P) and UJI (P11B2014-02) | ca_CA |
dc.format.extent | 6 p. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Royal Society of Chemistry | ca_CA |
dc.relation.isPartOf | Organic Chemistry Frontiers, 2(8), 2015 | ca_CA |
dc.rights | This journal is © the Partner Organisations 2015 Reproduced by permission of The Royal Society of Chemistry | ca_CA |
dc.rights.uri | http://rightsstatements.org/vocab/InC/1.0/ | * |
dc.subject | Efficient hydrogenation | ca_CA |
dc.subject | Bond activation | ca_CA |
dc.subject | Chiral alcohols | ca_CA |
dc.subject | Esters | ca_CA |
dc.subject | Mild | ca_CA |
dc.subject | Co2 | ca_CA |
dc.subject | Reduction | ca_CA |
dc.subject | Oxidation | ca_CA |
dc.subject | Methanol | ca_CA |
dc.subject | Ketones | ca_CA |
dc.title | Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1039/C5QO00137D | |
dc.rights.accessRights | info:eu-repo/semantics/openAccess | ca_CA |
dc.relation.publisherVersion | http://pubs.rsc.org/en/content/articlehtml/2015/qo/c5qo00137d | ca_CA |
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