A nano-sized Janus di-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core, and its coordina- tion to iridium
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Otros documentos de la autoría: Valdés Rivas, Hugo Christian; Poyatos, Macarena; Peris, Eduardo
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Mostrar el registro completo del ítemcomunitat-uji-handle:10234/9
comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/141972
comunitat-uji-handle4:10234/141976
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Título
A nano-sized Janus di-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core, and its coordina- tion to iridiumFecha de publicación
2015-04-21Editor
American Chemical SocietyISSN
0276-7333Cita bibliográfica
VALDÉS, Hugo; POYATOS, Macarena; PERIS, Eduardo. A Nanosized Janus Bis-N-heterocyclic Carbene Ligand Based on a Quinoxalinophenanthrophenazine Core, and Its Coordination to Iridium. Organometallics, 2015.Tipo de documento
info:eu-repo/semantics/articleVersión de la editorial
http://pubs.acs.org/doi/abs/10.1021/acs.organomet.5b00208Palabras clave / Materias
Resumen
A Janus-type bis-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core has been obtained and coordinated to iridium. The electronic properties of the ligand have been determined on the basis of ... [+]
A Janus-type bis-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core has been obtained and coordinated to iridium. The electronic properties of the ligand have been determined on the basis of an evaluation of the Tolman electronic parameter values. The new ligand disposes the two metals at a distance of 22.4 Å, significantly longer than in any of the related ligands reported so far. [-]
Publicado en
Organometallics, 2015, Vol. 34, n. 9Derechos de acceso
Copyright © 2015 American Chemical Society
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