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First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands

dc.contributor.authorMejuto, Carmen
dc.contributor.authorGuisado-Barrios, Gregorio
dc.contributor.authorGusev, Dmitry
dc.contributor.authorPeris, Eduardo
dc.date.accessioned2015-12-01T12:30:46Z
dc.date.available2015-12-01T12:30:46Z
dc.date.issued2015-07-24
dc.identifier.citationChem. Commun., 2015, 51, 13914ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/142045
dc.description.abstractThe preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag analogue to form the corresponding heteroleptic NHC–MIC silver cage in an unusual reaction involving the simultaneous exchange of the tris-NHC and tris-MIC ligands.ca_CA
dc.description.sponsorShipMINECO (CTQ2014-51999-P) and UJI (P11B2014-02).
dc.format.extent4 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfChemical Communication, 2015, 51ca_CA
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 4.0 Unported Licence.ca_CA
dc.rights.urihttp://creativecommons.org/licenses/by-nc/4.0/
dc.subjectN-Heterocyclic Carbenes
dc.subjectDicarbene Building-Blocks
dc.subjectMesoionic Carbenes
dc.subjectCatalytic-Properties
dc.subjectSupramolecular Chemistry
dc.subjectStructural Features
dc.subjectPolycarbene Ligands
dc.subjectTransition-Metals
dc.subjectMolecular Square
dc.subjectAU-I
dc.titleFirst homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligandsca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.description.versionPublished version
dc.identifier.doihttp://dx.doi.org/10.1039/c5cc05114b
dc.rights.accessRightsinfo:eu-repo/semantics/openAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114bca_CA


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