First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands

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comunitat-uji-handle:10234/9

comunitat-uji-handle2:10234/7053

comunitat-uji-handle3:10234/141972

comunitat-uji-handle4:10234/141976

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Title
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
Author (s)
 Mejuto, CarmenOrcidResearcherID;
 Guisado-Barrios, GregorioOrcidScopusResearcherID;
 Gusev, Dmitry;
 Peris, EduardoOrcidScopusResearcherID
Date
2015-07-24
Publisher
Royal Society of Chemistry
URI
http://hdl.handle.net/10234/142045
DOI
http://dx.doi.org/10.1039/c5cc05114b
Bibliographic citation
Chem. Commun., 2015, 51, 13914
Type
info:eu-repo/semantics/article
Publisher version
http://pubs.rsc.org/en/content/articlepdf/2015/cc/c5cc05114b
Subject
Abstract
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag ... [+]
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag analogue to form the corresponding heteroleptic NHC–MIC silver cage in an unusual reaction involving the simultaneous exchange of the tris-NHC and tris-MIC ligands. [-]
Is part of
Chemical Communication, 2015, 51
Rights
info:eu-repo/semantics/openAccess
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This article is licensed under a Creative Commons Attribution-NonCommercial 4.0 Unported Licence.
Except where otherwise noted, this item's license is described as This article is licensed under a Creative Commons Attribution-NonCommercial 4.0 Unported Licence.