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Unveiling the Importance of π-Stacking in Borrowing-Hydrogen Processes Catalysed by Iridium Complexes with Pyrene Tags
This work describes the preparation of a series of pyrene-tagged N-heterocyclic carbene complexes of iridium, and their use in two benchmark borrowing hydrogen reactions: the reduction of ketones by transfer hydrogenation ...
A nano-sized Janus di-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core, and its coordina- tion to iridium
(American Chemical Society, 2015-04-21)
A Janus-type bis-N-heterocyclic carbene ligand based on a quinoxalinophenanthrophenazine core has been obtained and coordinated to iridium. The electronic properties of the ligand have been determined on the basis of an ...