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First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
(Royal Society of Chemistry, 2015-07-24)
The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium)
salt allowed us to obtain the first homoleptic tris-MIC cylinder-like
cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag
analogue ...