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Unveiling the Importance of π-Stacking in Borrowing-Hydrogen Processes Catalysed by Iridium Complexes with Pyrene Tags
(Wiley, 2015-09-10)
This work describes the preparation of a series of pyrene-tagged N-heterocyclic carbene complexes of iridium, and their use in two benchmark borrowing hydrogen reactions: the reduction of ketones by transfer hydrogenation ...