Mostrar el registro sencillo del ítem
Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox Behavior
dc.contributor.author | Gushchin, Artem L. | |
dc.contributor.author | Laricheva, Yuliya A. | |
dc.contributor.author | Abramov, Pavel A. | |
dc.contributor.author | Virovets, Alexander V. | |
dc.contributor.author | Vicent Barrera, Cristian | |
dc.contributor.author | Sokolov, Maxim | |
dc.contributor.author | Llusar, Rosa | |
dc.date.accessioned | 2015-09-18T14:24:46Z | |
dc.date.available | 2015-09-18T14:24:46Z | |
dc.date.issued | 2014 | |
dc.identifier.issn | 1434-1948 | |
dc.identifier.uri | http://hdl.handle.net/10234/133229 | |
dc.description.abstract | Thiourea (tu) has been coordinated to the Mo3S44+ cluster unit to afford the new cluster compound [Mo3S4(tu)8(H2O)]Cl4·4H2O (1). The high substitutional lability of the thiourea ligands can be exploited to achieve smooth ligand substitution in the Mo3S4 cluster. The reactions of 1 with 1,10-phenanthroline (phen) and 2,2′-bipyridine (bpy) have resulted in new trisubstituted diimino complexes [Mo3S4Cl3L3]+ [L = phen (2), bpy (3)]. The crystal structure of [Mo3S4Cl3(phen)3]Cl·4H2O was determined by X-ray analysis. A solid-state cyclic voltammetry study of 2 shows a ligand-centered reversible two-electron reduction. DFT calculations for [Mo3S4Cl3(phen)3]+ and the 2e-reduced species [Mo3S4Cl3(phen)3]– support our interpretation of the reduction process. Compound 3 undergoes a reversible two-electron reduction, which is more metal-centered on the basis of DFT calculations. | ca_CA |
dc.format.mimetype | application/pdf | ca_CA |
dc.language.iso | eng | ca_CA |
dc.publisher | Wiley | ca_CA |
dc.relation.isPartOf | European Journal of Inorganic Chemistry, 2014, vol. 2014, nº 25, p. 4093-4100 | |
dc.rights.uri | http://rightsstatements.org/vocab/CNE/1.0/ | * |
dc.subject | cluster compounds | ca_CA |
dc.subject | molybdenum | ca_CA |
dc.subject | S ligands | ca_CA |
dc.subject | N ligands | ca_CA |
dc.subject | redox chemistry | ca_CA |
dc.title | Homoleptic Molybdenum Cluster Sulfides Functionalized with Noninnocent Diimine Ligands: Synthesis, Structure, and Redox Behavior | ca_CA |
dc.type | info:eu-repo/semantics/article | ca_CA |
dc.identifier.doi | http://dx.doi.org/10.1002/ejic.201402343 | |
dc.rights.accessRights | info:eu-repo/semantics/restrictedAccess | ca_CA |
dc.relation.publisherVersion | http://onlinelibrary.wiley.com/doi/10.1002/ejic.201402343/abstract | ca_CA |
dc.type.version | info:eu-repo/semantics/publishedVersion | ca_CA |
Ficheros en el ítem
Ficheros | Tamaño | Formato | Ver |
---|---|---|---|
No hay ficheros asociados a este ítem. |
Este ítem aparece en la(s) siguiente(s) colección(ones)
-
QFA_Articles [813]
Articles de publicacions periòdiques