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dc.contributor.authorSinha, Narayan
dc.contributor.authorRoelfes, Florian
dc.contributor.authorHepp, Alexander
dc.contributor.authorMejuto, Carmen
dc.contributor.authorPeris, Eduardo
dc.contributor.authorHahn, F. Ekkehardt
dc.date.accessioned2015-06-19T14:52:09Z
dc.date.available2015-06-19T14:52:09Z
dc.date.issued2014
dc.identifier.issn0276-7333
dc.identifier.issn1520-6041
dc.identifier.urihttp://hdl.handle.net/10234/124464
dc.description.abstractThe metal-controlled self-assembly of nanometer-sized trinuclear cylinder-like assemblies is described. The 1,3,5-triphenylbenzene-derived trisimidazolium salt [1](PF6)3 reacts with 1.5 equiv of Ag2O to yield the trinuclear AgI hexacarbene complex [2](PF6)3, where three AgI ions are sandwiched in between two C3-symmetric tris-NHC ligands. Transmetalation of [2](PF6)3 with 3 equiv of [AuCl(SMe2)] or CuI yields the trinuclear AuI hexacarbene complex [3](PF6)3 or the trinuclear CuI hexacarbene complex [4](PF6)3, respectively, with retention of the metallosupramolecular structure. The 1,3,5-triphenylbenzene ligand in the gold complex adopts a nonplanar geometry to allow π interactions between the central phenyl rings.ca_CA
dc.format.extent7 p.ca_CA
dc.language.isoengca_CA
dc.publisherAmerican Chemical Societyca_CA
dc.relation.isPartOfOrganometallics, 2014, 33 (23), pp 6898–6904ca_CA
dc.rightsCopyright © 2014 American Chemical Societyca_CA
dc.titleSynthesis of nanometer-sized cylinder-like structures from a 1,3,5- triphenylbenzene-bridged tris-NHC ligand and AgI , AuI , and CuIca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1021/om500973b
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.acs.org/doi/abs/10.1021/om500973bca_CA


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