Synthesis of nanometer-sized cylinder-like structures from a 1,3,5- triphenylbenzene-bridged tris-NHC ligand and AgI , AuI , and CuI
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Other documents of the author: Sinha, Narayan; Roelfes, Florian; Hepp, Alexander; Mejuto, Carmen; Peris, Eduardo; Hahn, Franz Ekkehardt
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comunitat-uji-handle2:10234/7053
comunitat-uji-handle3:10234/8639
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http://dx.doi.org/10.1021/om500973b |
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Title
Synthesis of nanometer-sized cylinder-like structures from a 1,3,5- triphenylbenzene-bridged tris-NHC ligand and AgI , AuI , and CuIAuthor (s)
Date
2014Publisher
American Chemical SocietyISSN
0276-7333; 1520-6041Type
info:eu-repo/semantics/articlePublisher version
http://pubs.acs.org/doi/abs/10.1021/om500973bAbstract
The metal-controlled self-assembly of nanometer-sized
trinuclear cylinder-like assemblies is described.
The 1,3,5-triphenylbenzene-derived trisimidazolium salt
[1](PF6)3 reacts with 1.5 equiv of Ag2O to yield the ... [+]
The metal-controlled self-assembly of nanometer-sized
trinuclear cylinder-like assemblies is described.
The 1,3,5-triphenylbenzene-derived trisimidazolium salt
[1](PF6)3 reacts with 1.5 equiv of Ag2O to yield the trinuclear
AgI hexacarbene complex [2](PF6)3, where three AgI ions are
sandwiched in between two C3-symmetric tris-NHC ligands.
Transmetalation of [2](PF6)3 with 3 equiv of [AuCl(SMe2)] or
CuI yields the trinuclear AuI hexacarbene complex [3](PF6)3 or
the trinuclear CuI hexacarbene complex [4](PF6)3, respectively,
with retention of the metallosupramolecular structure. The
1,3,5-triphenylbenzene ligand in the gold complex adopts a
nonplanar geometry to allow π interactions between the central phenyl rings. [-]
Is part of
Organometallics, 2014, 33 (23), pp 6898–6904Rights
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