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dc.contributor.authorGonell Gómez, Sergio
dc.contributor.authorPeris, Eduardo
dc.date.accessioned2015-06-18T06:41:28Z
dc.date.available2015-06-18T06:41:28Z
dc.date.issued2014-07-15
dc.identifier.citationGONELL GÓMEZ, S.; PERIS FAJARNÉS, E. Pyrene-Based Mono- and Di-N-Heterocyclic Carbene Ligand Complexes of Ruthenium for the Preparation of Mixed Arylated/Alkylated Arylpyridines. ACS Catalysis, 2014, 4 (8), pp. 2811-2817ca_CA
dc.identifier.urihttp://hdl.handle.net/10234/123963
dc.description.abstractBy using two pyrene-based mono- and di-N-heterocyclic carbene ligands, two ruthenium complexes (one monometallic and the other dimetallic) have been obtained and fully characterized. The molecular structure of the dimetallic complex has been determined by means of X-ray diffraction studies. The electrochemical studies reveal that the metal–metal communication in the dimetallic complex is weak. The catalytic activity of both complexes has been tested in the arylation of arylpyridines with aryl halides and in the hydroarylation of alkenes, where they showed similar activity. The sequential combination of these two catalytic processes (hydroarylation of alkenes followed by arylation of the resulting alkyl-substituted arylpyridine) allowed the preparation of mixed arylated/alkylated arylpyridines. In this tandem process, the dimetallic complex afforded activity higher than that of the monometallic complex. The activity was compared to that shown by the [RuCl2(p-cymene)]2 complex. This reaction constitutes an efficient method for reaching unsymmetrically substituted arylpyridines.ca_CA
dc.format.extent7 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherACS Publicationsca_CA
dc.relation.isPartOfACS Catalysis, 2014, 4 (8)ca_CA
dc.subjectRutheniumca_CA
dc.subjectN-heterocyclic carbeneca_CA
dc.subjectJanusca_CA
dc.subjectTandemca_CA
dc.subjectArylation of arylpyridinesca_CA
dc.subjectHydroarylation of alkenesca_CA
dc.titlePyrene-Based Mono- and Di-N-Heterocyclic Carbene Ligand Complexes of Ruthenium for the Preparation of Mixed Arylated/Alkylated Arylpyridinesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1021/cs500735u
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.acs.org/doi/abs/10.1021/cs500735uca_CA


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