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dc.contributor.authorPoyatos, Macarena
dc.contributor.authorPrades Ferrer, Amparo
dc.contributor.authorGonell Gómez, Sergio
dc.contributor.authorGusev, Dmitry G.
dc.contributor.authorPeris, Eduardo
dc.date.accessioned2015-03-30T12:07:13Z
dc.date.available2015-03-30T12:07:13Z
dc.date.issued2012
dc.identifier.issn2041-6520
dc.identifier.urihttp://hdl.handle.net/10234/116822
dc.description.abstractThe reaction of a series of imidazolidines with chloro-complexes of Ir, Rh and Ru affords the clean generation of the corresponding monohydrido metal species. Computational analysis of the reduction process suggests that the reaction proceeds via imidazolidine coordination followed by β-hydride elimination, affording the metal hydride and the imidazolinium cation as the only reaction products. The application of imidazolidines for reduction of transition-metal halides represents a principally new method for selective generation of monohydrides. No over-reduction takes place even when using a large excess of the imidazolidine.ca_CA
dc.format.extent4 p.ca_CA
dc.format.mimetypeapplication/pdfca_CA
dc.language.isoengca_CA
dc.publisherRoyal Society of Chemistryca_CA
dc.relation.isPartOfChemical Science, 4, 3, p. 1300-1303ca_CA
dc.rightsThis journal is copyright The Royal Society of Chemistry 2012ca_CA
dc.titleImidazolidines as hydride sources for the formation of late transition-metal monohydridesca_CA
dc.typeinfo:eu-repo/semantics/articleca_CA
dc.identifier.doihttp://dx.doi.org/10.1039/C2SC01017H
dc.rights.accessRightsinfo:eu-repo/semantics/restrictedAccessca_CA
dc.relation.publisherVersionhttp://pubs.rsc.org/en/content/articlelanding/2012/sc/c2sc01017h#!divAbstractca_CA


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