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First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
Corberán Roc, Rosa; Marrot, Sebastien; Dellus, Nicolas; Merceron-Saffon, Nathalie; Kato, Tsuyoshi; Peris, Eduardo; Baceiredo, Antoine American Chemical Society (2009)Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes have ...