Listar por autoría "8eddbe17-1d70-40c8-a858-a8e5dbd36de7"
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Mechanistic implications of the enantioselective addition of alkylzinc reagents to aldehydes catalyzed by nickel complexes with a-amino amide ligands
Escorihuela, Jorge; Burguete, M. Isabel; Ujaque, Gregori; Lledós, Agustí; Luis, Santiago V. The Royal Society of Chemistry (2016-11)The enantioselective alkylation of aldehydes catalysed by nickel(II)-complexes derived from α-amino amides was studied by means of density functional theory (DFT) and ONIOM (B3LYP:UFF) calculations. A mechanism was proposed ... -
New chiral tetraaza ligands for the efficient enantioselective addition of dialkylzinc to aromatic aldehydes
Burguete, M. Isabel; Escorihuela, Jorge; Luis, Santiago V.; Lledós, Agustí; Ujaque, Gregori Elsevier (2008)A series of chiral tetraaza ligands were studied for the enantioselective addition of dialkylzinc to aldehydes. These bis(amino amide) ligands show high enantioselectivity in the addition of organozincs to aromatic aldehydes. ...