Listar por autoría "74259d89-ed52-47af-b64b-d1d71326ec46"
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Cuboidal Mo3S4 and Mo3NiS4 Complexes Bearing Dithiophosphates and Chiral Carboxylate Ligands: Synthesis, Crystal Structure and Fluxionality
Hernández Molina, Rita; González Platas, Javier; Kovalenko, Konstantin A.; Sokolov, Maxim; Llusar, Rosa; Vicent Barrera, Cristian Wiley (2011-02)New triangular Mo and W cluster complexes incorporating (S)-lactic acid (HLac), [Mo3S4(μ-Lac)(dtp)3(py)] (1) and [W3S4(μ-Lac)(dtp)3(py)] (2), were prepared [dtp = (EtO)2PS2]. Analogous synthetic procedures were adapted for ... -
Heterometallic Cuboidal Clusters M3M‘Q4 (M = Mo, W; M‘= Sn, Pb, As, Sb; Q = S, Se): From Coordination Compounds to Supramolecular Adducts
Hernández Molina, Rita; Kalinina, Irina V.; Abramov, Pavel A.; Sokolov, Maxim; Virovets, Alexander V.; González Platas, Javier; Llusar, Rosa; Polo Ortiz, Victoriano; Vicent Barrera, Cristian; Fedin, Vladimir P. American Chemical Society (2008)Reactions of the incomplete cuboidal clusters [M3Q4(acac)3(py)3]+ (M = Mo, W; Q = S, Se) with group 14 and 15 metal complexes with the s2p0 electronic configuration (AsPh3, SbPh3, SbCl3, SbI3, PbI3-, SnCl3-) led to heterometal ... -
Isolation of a New Cs-Symmetrized Mo3(μ3-S)(μ-S)(μ-S2)2 Structural Type Through Complementary Association with a Cubane-Type Mo3NiS4 Cluster
Hernández Molina, Rita; González Platas, Javier; Vicent Barrera, Cristian Wiley (2012)A new cluster of formula {[Mo3(μ3-S)(μ-S)(μ-S2)2(dtp)3(μ-OAc)][Mo3NiS4(dtp)3(μ-OAc)(CH3CN)]} (1; dtp = diethyl dithiophosphate; OAc = acetate) comprising the novel Cs-symmetrized Mo3(μ3-S)(μ-S)(μ-S2)2 structural type ... -
Selective synthesis of triangular cluster oxido-sulfidocomplexes of Mo and W: High yield preparations of [Mo3O2S2(H2O)9]4+, [W3O2S2(H2O)9]4+, [W2MoO2S2(H2O)9]4+ and their derivatization
Abramov, Pavel A.; Sokolov, Maxim; Hernández Molina, Rita; Vicent Barrera, Cristian; Virovets, Alexander V.; Naumov, Dmitry Yu; Gili, Pedro; González Platas, Javier; Fedin, Vladimir P. Elsevier (2010)Reaction of [Mo2O2(μ-S)2(H2O)6]2+ with Mo(CO)6 or metallic Mo under hydrothermal conditions (140 °C, 4 M HCl) gives oxido-sulfido cluster aqua complex [Mo3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ (1). Similarly, [W3(μ3-S)(μ-O)2(μ-S)(H2O)9]4+ ...