Listar por autoría "0bfbed19-42cc-4f5a-a735-38cdbf1a76b6"
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A Shape‐Adaptable Organometallic Supramolecular Coordination Cage for the Encapsulation of Fullerenes
Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo Wiley (2018-10-01)The development of three‐dimensional supramolecular coordination complexes (SCCs), with cavities suitable for guest binding, is of great interest because these materials are useful in a large number of applications. Herein, ... -
A Sustainable Approach to Selective Hydrogenation of Unsaturated Esters and Aldehydes with Ruthenium Catalysts
Passos, Lucas H. R.; Martínez Agramunt, Víctor; Gusev, Dmitry; Peris, Eduardo; dos Santos, Eduardo Wiley (2023-05-12)The reduction of esters and aldehydes to alcohols is an important reaction in the chemical industry to produce a wide range of bulk and fine chemicals. Herein, the unexpected behavior of three state-of-the-art, commercially ... -
Ferrocenyl-Imidazolylidene Ligand for Redox-Switchable Gold-Based Catalysis. A Detailed Study on the Redox-Switching Abilities of the Ligand
Ibáñez, Susana; Poyatos, Macarena; Dawe, Louise N.; Gusev, Dmitry; Peris, Eduardo American Chemical Society (2016)An imidazolium salt with a fused benzoferrocenyl was synthesized. This compound was used as an N-heterocyclic carbene (NHC) precursor, and the related ferrocenyl-imidazolylidene complexes Fc-NHC-MLn (MLn = IrCl(COD), ... -
First homoleptic MIC and heteroleptic NHC-MIC coordination cages from 1,3,5-triphenylbenzene-bridged tris-MIC and tris-NHC ligands
Mejuto, Carmen; Guisado-Barrios, Gregorio; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2015-07-24)The preparation of a triphenylbenzene-bridged tris-(1,2,3-triazolium) salt allowed us to obtain the first homoleptic tris-MIC cylinder-like cages of Ag and Au. The silver MIC-based cage reacts with the trisNHC-Ag analogue ... -
Gold(I) Metallo‐Tweezers for the Recognition of Functionalized Polycyclic Aromatic Hydrocarbons by Combined π–π Stacking and H‐Bonding
Biz, Chiara; Ibáñez, Susana; Poyatos, Macarena; Gusev, Dmitry; Peris, Eduardo Wiley (2017)Two gold(I)‐based metallo‐tweezers with bis(Au−NHC) pincers and a carbazole connector have been obtained and used for the recognition of polycyclic aromatic hydrocarbons (PAHs). In the case of the tweezer with pyrene–NHC ... -
Imidazolidines as hydride sources for the formation of late transition-metal monohydrides
Poyatos, Macarena; Prades Ferrer, Amparo; Gonell, Sergio; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2012)The reaction of a series of imidazolidines with chloro-complexes of Ir, Rh and Ru affords the clean generation of the corresponding monohydrido metal species. Computational analysis of the reduction process suggests that ... -
Ion Mobility Mass Spectrometry Uncovers Guest-Induced Distortions in a Supramolecular Organometallic Metallosquare
Vicent Barrera, Cristian; Martínez Agramunt, Víctor; Gandhi, Viraj; Larriba, Carlos; Gusev, Dmitry; Peris, Eduardo Wiley (2021)The encapsulation of the tetracationic palladiummetallosquare with four pyrene-bis-imidazolylidene ligands[1]4+with aseries of organic molecules was studied byElectrosprayionization Travelling Wave Ion-Mobility MassSpectrometry ... -
Ruthenium complexes with an N-heterocyclic carbene NNC-pincer ligand: preparation and catalytic properties
Mejuto, Carmen; García-Eleno, Marco A.; Guisado-Barrios, Gregorio; Spasyuk, Denis; Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2015-06)1-Methyl-3-(2-((pyridin-2-ylmethylene)amino)ethyl)-1H-imidazol-3-ium bromide was prepared and used as an N-heterocyclic carbene NNC-pincer ligand precursor. Depending on the coordination strategy, a monometallic ... -
The Tolman electronic parameter (TEP) and the metal–metal electronic communication in ditopic NHC complexes
Gusev, Dmitry; Peris, Eduardo Royal Society of Chemistry (2013)Whereas the electronic communication between metals in dimetallic organometallic compounds is often assessed through cyclic voltammetric measurements, we have found that the variations in the Tolman electronic parameter ... -
Tuning the Catalytic Activity of a Pincer Complex of Rhodium(I) by Supramolecular and Redox Stimuli
Martínez-Vivas, Sebastián; Gusev, Dmitry; Poyatos, Macarena; Peris, Eduardo Wiley (2023)We report the rhodium(I) complex [Rh(CNC−NDI)(CO)]+, in which CNC−NDI refers to a pincer-CNC ligand decorated with a naphthalenediimide moiety. Due to the presence of the planar CNC ligand and the naphthalenediimide moiety, ... -
Unexpected influence of substituents on the binding affinities of polycyclic aromatic hydrocarbons with a tetra-Au(I) metallorectangle
Ibáñez, Susana; Gusev, Dmitry; Peris, Eduardo (2020-11-02)A tetra-gold supramolecular organometallic cage constructed with two pyrene-bis-imidazolylidene ligands and two carbazolyl-bis-alkynyl linkers (1) was studied as host for a series of substituted polycyclic aromatic hydrocarbons ...