2024-03-29T05:21:09Zhttps://repositori.uji.es/oai/requestoai:repositori.uji.es:10234/969552022-10-10T07:53:34Zcom_10234_7053com_10234_9col_10234_8639
Repositori UJI
author
Corberán Roc, Rosa
author
Marrot, Sebastien
author
Dellus, Nicolas
author
Merceron-Saffon, Nathalie
author
Kato, Tsuyoshi
author
Peris, Eduardo
author
Baceiredo, Antoine
2014-07-02T12:07:21Z
2014-07-02T12:07:21Z
2009
0276-7333
http://hdl.handle.net/10234/96955
http://dx.doi.org/10.1021/om8008958
Three new carbodiphosphorane complexes, (PHCP)M(tBuO) (PHCP = carbodiphosphorane; M = Cu, Au) and (PHCP)CuCl, were readily prepared by reaction of the carbodiphosphorane 2 with CuCl or AuCl(Me2S). The three complexes have been fully characterized, and their crystal structures have been determined. The two tert-butoxide complexes were tested in the catalytic anti-Markovnikov hydroamination and hydroalkoxylation of acrylonitrile, involving the first catalytic application of a carbodiphosphorane complex reported to date.
eng
Copyright © 2008 American Chemical Society
First Cyclic Carbodiphosphoranes of Copper(I) and Gold(I) and Their Application in the Catalytic Cleavage of X−H Bonds (X = N and O)
info:eu-repo/semantics/article
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