2024-03-29T07:47:08Zhttps://repositori.uji.es/oai/requestoai:repositori.uji.es:10234/1231032020-03-23T12:20:13Zcom_10234_7053com_10234_9col_10234_8639
Repositori UJI
author
Bezuidenhout, Daniela
author
Kleinhans, George
author
Guisado-Barrios, Gregorio
author
Liles, David C.
author
Üng, Gaël
author
Bertrand, Guy
2015-06-11T07:25:37Z
2015-06-11T07:25:37Z
2014
1359-73451364-548X
http://hdl.handle.net/10234/123103
http://dx.doi.org/10.1039/c3cc49385g
The synthesis and X-ray crystal structure of a potassium adduct of a monoanionic CNC-pincer ligand featuring two mesoionic carbenes is reported. Owing to the peculiar electronic and steric properties of this ligand, the first neutral stable Ni(II)-hydride, and an unusual Cu(II) complex displaying a seesaw geometry, have been isolated.
eng
© Royal Society of Chemistry 2015
n-heterocyclic carbenes
crystallographic characterization
hydride complexes
catalytic applications
palladium complexes
copper(i) complexes
carbonyl-compounds
olefin-metathesis
chemistry
crystal-structure
Isolation of a potassium bis(1,2,3-triazol-5-ylidene) carbazolide: a stabilizing pincer ligand for reactive late transition metal complexes
info:eu-repo/semantics/article
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