2024-03-29T02:26:02Zhttps://repositori.uji.es/oai/requestoai:repositori.uji.es:10234/652762024-02-12T17:11:55Zcom_10234_7013com_10234_9col_10234_8638
00925njm 22002777a 4500
dc
Sokolov, Maxim
author
Adonin, Sergey A.
author
Sinkevich, Pavel L.
author
Vicent Barrera, Cristian
author
Mainichev, Dmitry A.
author
Fedin, Vladimir P.
author
2012-06
ESI-MS based methodology for the rapid reactivity screening of [PW11O39RhCl]5− and [PW11O39Ir(H2O)]4− toward various metalation-intended substrates (reagents with an activated C–H bond, boronic acids and organotin compounds) is presented. Formation of a series of new organometallic POM derivatives with Rh–R (R = malonate, phenylacetate, CH3, Ph, ferrocenyl) and Ir–R (R = CH3) bonds is reported.
http://hdl.handle.net/10234/65276
http://dx.doi.org/10.1039/C2DT30655G
Organometallic derivatives of Rh- and Ir-substituted polyoxotungstates with Keggin structure: reactivity screening by electrospray ionization mass-spectrometry