2024-03-29T12:43:14Zhttps://repositori.uji.es/oai/requestoai:repositori.uji.es:10234/485782022-10-10T07:53:34Zcom_10234_7013com_10234_9col_10234_8638
00925njm 22002777a 4500
dc
Prades Ferrer, Amparo
author
Peris, Eduardo
author
albrecht, martin
author
2011-02-10
A series of “RuII(η6-arene)” complexes with 1,2,3-triazolylidene ligands have been prepared and fully characterized. The molecular structure of one of the new complexes has been determined by means of X-ray diffractrometry. The new complexes have been tested in a set of catalytic reactions involving alcohols and amines as substrates, including (i) base-free oxidation of benzylic alcohols to benzaldehydes, (ii) homocoupling of amines to form imines, and (iii) oxidative coupling of amines and alcohols to form amides. The results show the high versatility of the catalysts used and illustrate the application potential of 1,2,3-triazolylidene ligands in the design of effective homogeneous catalysts.
Organometallics 2011 30 (5), 1162-1167
http://hdl.handle.net/10234/48578
http://dx.doi.org/10.1021/om101145y
Organometallic and Organometalloidal Compounds
Oxidations and Oxidative Couplings Catalyzed by Triazolylidene Ruthenium Complexes